Silver acetylide - Wikipedia
Silver acetylide is an inorganic chemical compound with the formula Ag 2 C 2, a metal acetylide. The compound can be regarded as a silver salt of the weak acid, acetylene. The salt's anion consists of two carbon atoms linked by a triple bond, thus, its structure is [Ag+]2[−C≡C−].
The organic chemistry of silver acetylides - RSC Publishing
Silver acetylides are now seen as promising tools in organic chemistry. This critical review focuses on this emerging field, and, with emphasis on mechanistic aspects, cover the synthesis of silver acetylides, their applications in organic chemistry and reactions involving silver salts as catalysts where silver acetylides are probable ...
Silver acetylide - Sciencemadness Wiki
2023年6月2日 · Silver acetylide is a white to gray solid, odorless and insoluble in water and solvents. Explosive Silver acetylide is highly sensitive to heat and mechanical shock when dry, though less so when wet.
Acetylide - Wikipedia
In chemistry, an acetylide is a compound that can be viewed as the result of replacing one or both hydrogen atoms of acetylene (ethyne) HC≡CH by metallic or other cations. The term is also used, more loosely, for any compound obtained in the same way from an acetylene derivative RC≡CH, where R is some organic side chain. [1]
Silver acetylide - Wikiwand
Silver acetylide is an inorganic chemical compound with the formula Ag 2 C 2, a metal acetylide. The compound can be regarded as a silver salt of the weak acid, acetylene. The salt's anion consists of two carbon atoms linked by a triple bond, thus, its structure is [Ag+]2[−C≡C−].
9.7: Alkyne Acidity - Formation of Acetylide Anions
In the laboratory component of this course, you will use the formation of an insoluble silver acetylide as a method for distinguishing terminal alkynes from alkenes and non-terminal alkynes: Metal acetylides are explosive when dry.
The organic chemistry of silver acetylides - PubMed
This critical review focuses on this emerging field, and, with emphasis on mechanistic aspects, cover the synthesis of silver acetylides, their applications in organic chemistry and reactions involving silver salts as catalysts where silver acetylides are probable intermediates.
Soluble Silver Acetylide for the Construction and Structural …
Unprecedented organic-solvent-soluble silver acetylides are designed and used to construct high-nuclearity homoleptic silver acetylide clusters. Structural analysis of these all-alkynyl-protected silver clusters provides crucial insights into silver chemistry.
Structural Variation in Silver Acetylide Complexes: Syntheses and …
1996年1月23日 · Silver acetylides are readily prepared by the substitution of the Cp group of CpAgPR3. The structures of [Ph3PAgC⋮CPh]4·3.5THF (2) and [Me3PAgC⋮CSiMe3]∞ (4) illustrate that these complexes are cons...
Silver acetylide | C2HAg | CID 25150847 - PubChem
2021年5月7日 · Silver acetylide | C2HAg | CID 25150847 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.